Highly active oxime-derived palladacycle complexes for Suzuki-Miyaura and Ullmann-type coupling reactions.

@article{Alonso2002HighlyAO,
  title={Highly active oxime-derived palladacycle complexes for Suzuki-Miyaura and Ullmann-type coupling reactions.},
  author={Diego A. Alonso and Carmen N{\'a}jera and Ma Carmen Pacheco},
  journal={The Journal of organic chemistry},
  year={2002},
  volume={67 16},
  pages={5588-94}
}
Oxime-derived chloro-bridged palladacycles 12 and 13 are efficient complexes for the Suzuki-Miyaura reactions of aryl-, allyl-, and benzyl halides with arylboronic acids. The isolated catalysts are thermally stable, not sensitive to air or moisture, and easily accessible from inexpensive starting materials. The reaction can be performed under aerobic… CONTINUE READING