Highlight on the solution processes occurring on silver(i)-assembling porphyrins in the presence of an excess of silver salt.


Coordination cages obtained upon complexation of pyridyl functionalized porphyrins by Ag+ disassemble when overtaking a 1 : 2 stoichiometric amount of silver salt. An excess of Ag+ then leads to unusual chemical processes, here analyzed in detail, which permanently transform the monomeric porphyrins. The observed processes, discussed with reference to model… (More)
DOI: 10.1039/c7dt00974g


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