High-valent iron and manganese complexes of corrole and porphyrin in atom transfer and dioxygen evolving catalysis.


Manganese(V) imido complexes of 5,10,15-tris(pentafluorophenyl)corrole (H(3)tpfc) can be prepared by the reaction of Mn(III)(tpfc) and organic nitrene generated from either photolytic or thermal activation of organic azides. The terminal imido complexes of manganese(V) were among the first structurally characterized examples of Mn(V) terminal imido… (More)
DOI: 10.1039/c0dt01341b


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