High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture.

  title={High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture.},
  author={Rahul Banerjee and Anh Phan and Bo Wang and Carolyn B. Knobler and Hiroyasu Furukawa and M. O'Keeffe and Omar M Yaghi},
  volume={319 5865},
A high-throughput protocol was developed for the synthesis of zeolitic imidazolate frameworks (ZIFs). Twenty-five different ZIF crystals were synthesized from only 9600 microreactions of either zinc(II)/cobalt(II) and imidazolate/imidazolate-type linkers. All of the ZIF structures have tetrahedral frameworks: 10 of which have two different links (heterolinks), 16 of which are previously unobserved compositions and structures, and 5 of which have topologies as yet unobserved in zeolites. Members… CONTINUE READING
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