High switchable dielectric phase transition originating from distortion in inorganic-organic hybrid materials (H2dabco-C2H5) [MIICl4] (M = Co, Zn).

@article{Ji2018HighSD,
  title={High switchable dielectric phase transition originating from distortion in inorganic-organic hybrid materials (H2dabco-C2H5) [MIICl4] (M = Co, Zn).},
  author={Qin Ji and Lin-Hai Li and Siyu Deng and Xing-Xing Cao and Lizhuang Chen},
  journal={Dalton transactions},
  year={2018},
  volume={47 16},
  pages={
          5630-5638
        }
}
Two phase transition materials (H2dabco-C2H5)[ZnCl4] and (H2dabco-C2H5)[CoCl4] were synthesized and characterized. Differential scanning calorimetry detected that the two compounds underwent reversible phase transitions at 245 K and 261 K, respectively. The temperature dependence of the dielectric measurements also confirmed the phase transition. Variable-temperature single-crystal X-ray diffraction suggested that the two compounds underwent the same phase transitions from the space group Pnma… 
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