High-spin manganese(II) complexes of an amido/bis(phosphine) PNP ligand.


Syntheses of several Mn complexes supported by a monoanionic amido/bis(phosphino) PNP ligand (PNP = [2-P(CHMe(2))(2)-4-MeC(6)H(3)](2)N) from anhydrous MnCl(2) are reported. Treatment of (PNP)Li (2) with MnCl(2) in tetrahydrofuran (THF) led to isolation of either (PNP)Mn(mu-Cl)(2)Li(THF)(2) (5) or (PNP)MnCl (6), depending on the workup. Reaction of 6 with 2… (More)
DOI: 10.1021/ic1004424


Figures and Tables

Sorry, we couldn't extract any figures or tables for this paper.

Slides referencing similar topics