High-resolution electron spectroscopy and sigma/pi structures of M(pyridine) and M+(pyridine) (M = Li, Ca, and Sc) complexes.

Abstract

Metal-pyridine (metal = Li, Ca, and Sc) complexes are produced in laser-vaporization molecular beams and studied by pulsed-field-ionization zero-electron-kinetic-energy (ZEKE) spectroscopy and theoretical calculations. Both sigma and pi structures are considered for the three complexes by theory, and preferred structures are determined by the combination of… (More)
DOI: 10.1063/1.3109688

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