High-pressure phase transitions in rubidium and caesium hydroxides.

  • Andreas Hermann
  • Published 2016 in Physical chemistry chemical physics : PCCP

Abstract

A computational investigation of the high-pressure phase sequence of the heaviest alkali hydroxides, RbOH and CsOH, shows that the phase diagram of both compounds is richer than hitherto thought. First-principles calculations suggest, based on energetics and comparisons to experimental diffraction and spectroscopy signatures, that the high-pressure phase… (More)
DOI: 10.1039/c6cp03203f

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