High-efficiency preparation of macrocyclic diblock copolymers via selective click reaction in micellar media.

Abstract

We report a novel strategy for the high-efficiency preparation of macrocyclic diblock copolymers at relatively high concentrations via the combination of supramolecular self-assembly and "selective" click reactions, relying on the fine control of spatial accessibility between terminal reactive groups. The linear precursor, alpha-alkynyl-omega-azido… (More)
DOI: 10.1021/ja808772z

Topics

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