High and selective CO2 uptake in a cobalt adeninate metal-organic framework exhibiting pyrimidine- and amino-decorated pores.

@article{An2010HighAS,
  title={High and selective CO2 uptake in a cobalt adeninate metal-organic framework exhibiting pyrimidine- and amino-decorated pores.},
  author={Jihyun An and Steven J Geib and Nathaniel L Rosi},
  journal={Journal of the American Chemical Society},
  year={2010},
  volume={132 1},
  pages={38-9}
}
The synthesis and structure of Co(2)(ad)(2)(CO(2)CH(3))(2) x 2 DMF x 0.5 H(2)O (bio-MOF-11) is described. Pyrimidine and amino groups of adeninate (ad) decorate the pores of the framework. The porosity of this material was studied, and its CO(2) and H(2) adsorption properties were evaluated. bio-MOF-11 exhibits a high heat of adsorption for CO(2) (approximately 45 kJ/mol), a high CO(2) capacity (approximately 6 mmol/g, 273 K), and exceptional selectivity for CO(2) over N(2) at 273 K (81:1) and… CONTINUE READING
Highly Cited
This paper has 65 citations. REVIEW CITATIONS

From This Paper

Figures, tables, and topics from this paper.

Citations

Publications citing this paper.
Showing 1-10 of 36 extracted citations

65 Citations

01020'11'13'15'17
Citations per Year
Semantic Scholar estimates that this publication has 65 citations based on the available data.

See our FAQ for additional information.

Similar Papers

Loading similar papers…