Hierarchical Self-Assembly of Disc-Rod Shape Amphiphiles Having Hexa-peri-hexabenzocoronene and a Relatively Long Rod.


Two disc-rod shape amphiphiles consisting of hexa-peri-hexabenzocoronene (HBC) and a nanosized rodlike mesogen were designed and synthesized. Thermotropic phase behaviors were carefully studied. Despite significant steric mismatch between the discs and rods, hierarchical structures were observed for both disc-rod shape amphiphiles at ambient temperature and… (More)
DOI: 10.1021/acs.langmuir.7b00456


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