Hexaphenylbenzene as a rigid template for the straightforward syntheses of "star-shaped" glycodendrimers.


Original glycodendrimers emanating from propargylated hexaphenylbenzene cores and containing up to 54 peripheral sugar ligands have been synthesized by Cu(I)-catalyzed [1,3]-dipolar cycloadditions using both convergent and divergent approaches. 
DOI: 10.1021/jo102215y


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