Heterometallic thiacalix[4]arene-supported Na2Ni(II)12Ln(III)2 clusters with vertex-fused tricubane cores (Ln = Dy and Tb).

Abstract

Two heterometallic thiacalix[4]arene-supported complexes possess a trinary-cubane core composed of one [Ni(2)Ln(2)] cubane unit and two [NaNi(2)Ln] cubane units sharing one Ln(III) ion (Ln = Dy and Tb). Only the Dy(III) complex exhibits slow magnetic relaxation behaviour of single molecule magnet nature. 
DOI: 10.1039/c2cc32360e

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