Heterogeneously catalyzed aerobic cross-dehydrogenative coupling of terminal alkynes and monohydrosilanes by gold supported on OMS-2.

@article{Yamaguchi2013HeterogeneouslyCA,
  title={Heterogeneously catalyzed aerobic cross-dehydrogenative coupling of terminal alkynes and monohydrosilanes by gold supported on OMS-2.},
  author={Kazuya Yamaguchi and Ye Wang and Takamichi Oishi and Yoshiyuki Kuroda and Noritaka Mizuno},
  journal={Angewandte Chemie},
  year={2013},
  volume={52 21},
  pages={5627-30}
}
Alkynylsilane derivatives are an important class of compounds and have been used not only as versatile alkynyl nucleophiles for common organic synthesis but also as siliconprotected intermediates for olygo-yne polymers, silylene– acetylene copolymers, and acetylene-bridged organometallic complexes. Up to the present, the vast majority have commonly used… CONTINUE READING