Heterochiral triangulo nickel complex as evidence of a large positive nonlinear effect in catalysis.


A novel triangulo complex was generated by heating, in vacuo, a racemic C2-symmetric octahedral nickel(II) diamine complex. The trinuclear species was identified by single-crystal X-ray diffraction, which revealed a 2:1 ligand stereochemistry relationship in each unit. This solid-state structure evidences the hypothesis that a 1:2 stereochemical… (More)
DOI: 10.1021/ic7017727


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