Heterobimetallic (Imido)antimony/Lithium Cages Containing [Sb(NR)(3)](3-) Trianions.

Abstract

The reactions of [Sb(NMe(2))(3)] with the primary (amido)lithiums [PhCH(2)CH(2)N(H)Li](n)(), [CyN(H)Li](n)() (Cy = C(6)H(11)), [2,4-dmpN(H)Li](n)() [2,4-dmp = 2,4-(MeO)(2)C(6)H(3)], and [(t)()BuN(H)HLi](n)() give the heterobimetallic cage complexes [{Sb(NCH(2)CH(2)Ph)(3)}(2)Li(6).2THF] (1), [{Sb(NCy)(3)}(2)Li(6).2HNMe(2)].2C(6)H(5)CH(3) (2), [Sb{N(2,4-dmp… (More)

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