Heteroaryl bismuthines: a novel synthetic concept and metalπ heteroarene interactions.

@article{Preda2017HeteroarylBA,
  title={Heteroaryl bismuthines: a novel synthetic concept and metalπ heteroarene interactions.},
  author={Ana Maria Preda and Wolfgang B Schneider and Matthias Rainer and Tobias R{\"u}ffer and Dieter Schaarschmidt and Heinrich Lang and Michael Mehring},
  journal={Dalton transactions},
  year={2017},
  volume={46 25},
  pages={8269-8278}
}
The alkoxide Bi[OCMe2(2-C4H3S)]3 (1) is formed by the reaction of three equiv. of the alcohol HOCMe2(2-C4H3S) with Bi(OtBu)3 and subsequent hydrolysis provides the bismuth oxido cluster [Bi4O2{OCMe2(2-C4H3S)}8] (2). In contrast, the reaction of Bi(OtBu)3 and Bi[N(SiMe3)2]3 with the silanols HOSiMe2(2-C4H3X) (X = O, S, Se, and NMe), HOSiMe2(2-C4H2S-5-SiMe3… CONTINUE READING