Harnessing glycal-epoxide rearrangements: the generation of the AB, EF, and IJ rings of adriatoxin.

Abstract

workers from the digestive gland of the Adriatic mussel Mytilus galloprovincialis. Synthetically, our fascination with adriatoxin came out of an interest in determining whether our recently described coupling protocol, which leads to the pairing of two subunits and the generation of two additional rings, would enable us to carry out a convergent synthesis… (More)
DOI: 10.1002/anie.200803791

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