H2 interaction with divalent cations in isostructural MOFs: a key study for variable temperature infrared spectroscopy.

@article{Chavan2013H2IW,
  title={H2 interaction with divalent cations in isostructural MOFs: a key study for variable temperature infrared spectroscopy.},
  author={S. Chavan and O. Zavorotynska and C. Lamberti and S. Bordiga},
  journal={Dalton transactions},
  year={2013},
  volume={42 35},
  pages={
          12586-95
        }
}
Systematic studies of H2 adsorption by variable temperature infrared (VTIR) spectroscopy have added value in the characterization of hydrogen storage materials. As a key study to describe the potential of the method, here we report VTIR spectroscopy results of H2 adsorption at isostructural MOFs CPO-27-M (M = Mg, Mn, Co, Ni, Zn). The strongest perturbation of H2 vibrational frequency is due to the interaction with an open metal site. Although ionic radius is an empirical value, the direct… Expand
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