H2 interaction with divalent cations in isostructural MOFs: a key study for variable temperature infrared spectroscopy.

@article{Chavan2013H2IW,
  title={H2 interaction with divalent cations in isostructural MOFs: a key study for variable temperature infrared spectroscopy.},
  author={Sachin M Chavan and Olena Zavorotynska and Carlo Lamberti and Silvia Bordiga},
  journal={Dalton transactions},
  year={2013},
  volume={42 35},
  pages={
          12586-95
        }
}
Systematic studies of H2 adsorption by variable temperature infrared (VTIR) spectroscopy have added value in the characterization of hydrogen storage materials. As a key study to describe the potential of the method, here we report VTIR spectroscopy results of H2 adsorption at isostructural MOFs CPO-27-M (M = Mg, Mn, Co, Ni, Zn). The strongest perturbation of H2 vibrational frequency is due to the interaction with an open metal site. Although ionic radius is an empirical value, the direct… CONTINUE READING
1
Twitter Mention

References

Publications referenced by this paper.
SHOWING 1-3 OF 3 REFERENCES

Chavan , Characterization of Metal - organic Frameworks for Gas Storage and Catalysis applications , PhD thesis in Materials Science , University of Turin ( I ) , 2010 14 S . L . James

A. R. Millward, K. S. Park, +17 authors S. M. Cohen
  • 2011

Characterization of Metal-organic Frameworks for Gas Storage and Catalysis applications, PhD thesis in Materials

K. M. Thomas
  • Dalton Trans.,
  • 2009

3494. 3 M. Hirscher, Handbook of Hydrogen Storage; 1 ed.; Wiley-VCH

A. G. Wong-Foy, A. J. Matzger, O. M. Yaghi, J. Am
  • Weinheim,
  • 2006