H(2) ejection from polycyclic aromatic hydrocarbons: infrared multiphoton dissociation study of protonated 1,2-dihydronaphthalene.


1,2-Dihydronaphthalene (DHN) has been studied by matrix isolation infrared absorption spectroscopy, multiphoton infrared photodissociation (IRMPD) action spectroscopy, and density functional theory calculations. Formed by electrospray ionization, protonated 1,2-dihydronapthalene was injected into a Fourier transform ion cyclotron resonance mass spectrometer… (More)
DOI: 10.1021/ja808965x


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