Guided ion beam and theoretical study of the reactions of Os+ with H2, D2, and HD.

Abstract

Reactions of the third-row transition metal cation Os(+) with H(2), D(2), and HD to form OsH(+) (OsD(+)) were studied using a guided ion beam tandem mass spectrometer. A flow tube ion source produces Os(+) in its (6)D (6s(1)5d(6)) electronic ground state level. Corresponding state-specific reaction cross sections are obtained. The kinetic energy dependences… (More)
DOI: 10.1063/1.3669425

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