Guest Transport in a Nonporous Organic Solid via Dynamic van der Waals Cooperativity
@article{Atwood2002GuestTI, title={Guest Transport in a Nonporous Organic Solid via Dynamic van der Waals Cooperativity}, author={J. Atwood and L. Barbour and A. Jerga and B. L. Schottel}, journal={Science}, year={2002}, volume={298}, pages={1000 - 1002} }
A well-known organic host compound undergoes single-crystal–to–single-crystal phase transitions upon guest uptake and release. Despite a lack of porosity of the material, guest transport through the solid occurs readily until a thermodynamically stable structure is achieved. In order to actively facilitate this dynamic process, the host molecules undergo significant positional and/or orientational rearrangement. This transformation of the host lattice is triggered by weak van der Waals… CONTINUE READING
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