Ground state structures of Fe(2)O(4-6)(+) clusters probed by reactions with N(2).


Reactions of small cationic iron oxide clusters (Fe(2)O(4-6)(+)) with N(2) are investigated by experiments and first principle calculations. The cationic iron oxide clusters are generated by reaction of laser ablated iron plasma with O(2) in a supersonic expansion, and are reacted with N(2) in a fast flow reactor at near room temperature conditions. Cluster… (More)
DOI: 10.1021/jp810426s


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