Gold(I) and Gold(III) Complexes of Cyclic (Alkyl)(amino)carbenes

Abstract

The chemistry of Au(I) complexes with two types of cyclic (alkyl)(amino)carbene (CAAC) ligands has been explored, using the sterically less demanding dimethyl derivative Me2CAAC and the 2-adamantyl ligand AdCAAC. The conversion of (AdCAAC)AuCl into (AdCAAC)AuOH by treatment with KOH is significantly accelerated by the addition of tBuOH. (AdCAAC)AuOH is a… (More)

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@inproceedings{Romanov2015GoldIAG, title={Gold(I) and Gold(III) Complexes of Cyclic (Alkyl)(amino)carbenes}, author={A. N. Romanov and Manfred Bochmann}, booktitle={Organometallics}, year={2015} }