Gold(I) Chloride Complexes of Polyphosphine Ligands with Electron-Rich Arene Spacer: Gold–Arene Interactions

@article{Ni2012GoldICC,
  title={Gold(I) Chloride Complexes of Polyphosphine Ligands with Electron-Rich Arene Spacer: Gold–Arene Interactions},
  author={Qing-ling Ni and Xuan-Feng Jiang and Ting-Hong Huang and Xiu-Jian Wang and L. Gui and K. Yang},
  journal={Organometallics},
  year={2012},
  volume={31},
  pages={2343-2348}
}
The reactions of Au(tht)Cl (tht = tetrahydrothiophene) with the electron-rich-arene-spacer-containing polyphosphine ligands N,N′-bis((diphenylphosphino)methyl)benzene-1,4-diamine (Dpba), N,N′-bis((diphenylphosphino)methyl)naphthalene-1,5-diamine (Dpna), N,N,N′,N′- tetrakis((diphenylphosphino)methyl)benzene-1,4-diamine (Pbaa), N,N,N′,N′-tetrakis((diphenylphosphino)methyl)naphthalene-1,5-diamine (Pnaa), and N,N,N′,N′-tetrakis((diphenylphosphino)methyl)biphenyl-4,4′-diamine (Pbbaa) lead to [Dpba… Expand
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Helicenes with embedded phosphole units in enantioselective gold catalysis.
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