Glycosides of Monoallyl Diethylene Glycol. A New Type of Spacer Group for Synthetic Oligosaccharides

  title={Glycosides of Monoallyl Diethylene Glycol. A New Type of Spacer Group for Synthetic Oligosaccharides},
  author={Violeta Fern{\'a}ndez-Santana and J. R. Marino-albernas and vicente Verez-Bencomo and Carlos P{\'e}rez-Mart{\'i}nez},
  journal={Journal of Carbohydrate Chemistry},
Abstract The preparation of spacer-armed synthetic oligosaccharides, which can be coupled to either proteins or polymers for use respectively as immunogens or immunoadsorbants for affinity chromatography, is today an important field in chemistry. The methoxycarbonyloctyl glycosides developed by Lemieux and coworkers1 are frequently used and remain the most popular. Other glycosides with amide,2 thioether, 3 and ether4 type spacer groups have also been employed. Recently, an alternative to… 
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Immobilization of Reducing Oligosaccharides to Matrices by a Glycosylamide Linkage
A novel method is described for coupling of reducing oligosaccharides to matrices, which forms a glycosyl amide bond to the matrix and produced new matrices that were useful in affinity chromatography, e.g., for purification of lectins and antibodies.
A method for glycoconjugate synthesis
7-Formylheptyl glycosides of 2-acetamido-2-deoxy-β-d-glucopyranose andO-α-l-rhamnopyranosyl were synthesized and were coupled by reductive amination to bovine serum albumin and aminopropyl glass, respectively.
Synthesis and SOD-Like Activity of Monosaccharide Derived Thiosemicarbazones
Abstract The synthesis of new O-β-D-glucopyranosyl- and O-β-D-galactopyranosyl-2-hydroxyacetaldehyde thiosemicarbazones (5a,b) is reported. Oxidation of allyl glycoside 1 with KMnO4 followed by NaIO4
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Stripping and cleaning agent for removing dry-etching pho toresist residues, and a method for forming an aluminum based line pattern using the stripping and cleaning agent. The stripping and cleaning
United States Patent ( 19 )
59-83347 5/1984 60-131765 7/1985 63-124371 5/1988 1-112663 5/1989 230061 1/199


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