Glycosides of 8-hydroxy-3,6-dioxaoctanal. A synthesis of a new spacer for synthetic oligosaccharides.

  title={Glycosides of 8-hydroxy-3,6-dioxaoctanal. A synthesis of a new spacer for synthetic oligosaccharides.},
  author={vicente Verez-Bencomo and M T Campos-Valdes and J. R. Marino-albernas and Violeta Fern{\'a}ndez-Santana and M Hernandez-Rensoli and Carlos P{\'e}rez-Mart{\'i}nez},
  journal={Carbohydrate research},
7 Citations
A method for glycoconjugate synthesis
7-Formylheptyl glycosides of 2-acetamido-2-deoxy-β-d-glucopyranose andO-α-l-rhamnopyranosyl were synthesized and were coupled by reductive amination to bovine serum albumin and aminopropyl glass, respectively.
Synthesis of oligosaccharides with oligoethylene glycolspacers and their conversion into glycoconjugates usingN,N,N′,N′-tetramethyl(succinimido)u roniu mtetrafluoroborate as coupling reagent
Glycosides of glucose and lactose with di- and tetraethylene glycols, transformed into bifunctional (alcohol, ester) spacer molecules, have been synthesized using tetramethyl(succinimido)uronium tetrafluoroborate for the formation of an active ester.
Synthesis of the Vibrio Cholerae O1 Ogawa and Inaba Terminal Disaccharides With Dioxolane-Type Spacers and their Coupling to Proteins1
Abstract The disaccharide, which corresponds to the terminal fragment of the Vibrio cholerae O1 LPS, was prepared starting from the corresponding trichloroacetimidate derivative of the monosaccharide
Synthesis of the Trisaccharide α-l-Rha-(1-2)-α-l-Rha-(1-2)-α-L-Rha with a Dioxolane-Type Spacer-Arm1
Abstract The trisaccharide α-L-Rha-(1-2)-α-L-Rha-(1-2)-α-L-Rha with a dioxolane-type spacer was obtained by using the trichloroacetimidate method in all of the glycosidation steps. After


Glycosides of Monoallyl Diethylene Glycol. A New Type of Spacer Group for Synthetic Oligosaccharides
Abstract The preparation of spacer-armed synthetic oligosaccharides, which can be coupled to either proteins or polymers for use respectively as immunogens or immunoadsorbants for affinity
Synthetic oligosaccharides related to group B streptococcal polysaccharides. 3. Synthesis of oligosaccharides corresponding to the common polysaccharide antigen of group B streptococci
Preparation d'un tetrasaccharide constituant d'un antigene du streptocoque B, ainsi que de plusieurs di et tri- saccharides a partir de D-glucitol et d'accepteurs glycosyles
The Application of the Trichloroacetimidate Method to the Synthesis of α-D-Gluco- and α-D-Galactopyranosides
Abstract The trichloroacetimidate method has been applied to the construction of α-d-galacto- and α-d-glucopyranosides. The readily available β-trichloroacetimidates of