Glycidyl methacrylate derivatized xylan-rich hemicelluloses: synthesis and characterizations

@article{Peng2012GlycidylMD,
  title={Glycidyl methacrylate derivatized xylan-rich hemicelluloses: synthesis and characterizations},
  author={Xinwen Peng and Junli Ren and Linxin Zhong and Run-Cang Sun and Wenbin Shi and Bojie Hu},
  journal={Cellulose},
  year={2012},
  volume={19},
  pages={1361-1372}
}
In this paper, a novel type of hemicellulosic derivative containing polymerizable double bonds (C=C) was synthesized by chemical reaction of xylan-rich hemicelluloses and glycidyl methacrylate (GMA) in dimethyl sulfoxide (DMSO) in presence of catalysts. The chemical structure, reaction mechanism, and rheological properties of the derivative were investigated by means of FT-IR, 1H and 13C-NMR, DEPT 135 NMR, GC–MS and rheometer. The influence of the reaction conditions including reaction time… CONTINUE READING

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