Generation of thiyl radicals in a zinc(ii) porous coordination polymer by light-induced post-synthetic deprotection.

Abstract

Kinetic stabilisation of unstable chemical species in nanospace is of potential importance in the field of materials and synthetic chemistry, and porous coordination polymers (PCPs) represent a facile platform to provide such reaction fields. Thiyl radicals are important reactive substances that often play a leading role in organic and bioorganic chemistry… (More)
DOI: 10.1039/c8cc01837e

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