Generation of strength in a drying film: How fracture toughness depends on dispersion properties.
@article{BirkBraun2017GenerationOS,
title={Generation of strength in a drying film: How fracture toughness depends on dispersion properties.},
author={Natalie Birk-Braun and Kamran Yunus and Eric J. Rees and Wilhelm Schabel and Alexander F. Routh},
journal={Physical review. E},
year={2017},
volume={95 2-1},
pages={
022610
}
}The fracture toughness of colloidal films is measured by characterizing cracks which form during directional drying. Images from a confocal microscope are processed to measure the crack width as a function of distance from the crack tip. Applying theory for thin elastic films the fracture toughness is extracted. It is found that the fracture toughness scales with the particle size to the -0.8 power and that the critical energy release rate scales with the particle size to the -1.3 power. In…
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References
SHOWING 1-10 OF 25 REFERENCES
How to Reduce the Crack Density in Drying Colloidal Material
- Materials Science
- 2013
The drying of a colloidal dispersion can result in a gel phase defined as a porous matrix saturated in solvent. During the drying process, high mechanical stresses are generated. When these stresses…
Plasticity and fracture in drying colloidal films.
- PhysicsPhysical review letters
- 2013
It is shown that although the deformation around a crack tip has some features of brittle fracture, only 20%-30% of the crack opening is relieved when it is unloaded, which suggests that a film's fracture toughness may be increased by decreasing the interparticle adhesion.
Cracking in drying latex films.
- Materials Science, PhysicsLangmuir : the ACS journal of surfaces and colloids
- 2005
The critical stress at cracking and the accompanying crack spacing is calculated, in general agreement with the observed values, by employing the stress-strain relation for a drying latex film along with the well-known Griffith's energy balance concept.
Flow and fracture in drying nanoparticle suspensions.
- PhysicsPhysical review letters
- 2003
It is shown that the growth of cracks is limited by the advancement of the compaction front, which is governed by a balance of evaporation and flow of fluid at the drying surface.
Wavy cracks in drying colloidal films
- Physics
- 2011
Fracture mechanics successfully predicts when cracks will grow. Describing the path that cracks follow, however, has remained difficult. The study of crack paths has recently focused on a single…
Alternating crack propagation during directional drying.
- PhysicsLangmuir : the ACS journal of surfaces and colloids
- 2007
The propagation of fractures during the drying of a colloidal silica suspension confined in a vertical microtube is investigated, and the slow propagation of a fracture is followed by the rapid propagation of the other.
Imaging in-plane and normal stresses near an interface crack using traction force microscopy
- Materials ScienceProceedings of the National Academy of Sciences
- 2010
Traction force microscopy is extended to quantify the spatial distribution of all three components of the stress at the interface of two materials and extract the stress intensity factor.





