Generation of small gold clusters with unique geometries through cluster-to-cluster transformations: octanuclear clusters with edge-sharing gold tetrahedron motifs.

Abstract

Molecular gold clusters with defined nuclearity and geometrical structures have attracted continuing interest, due not only to the fundamental aspects of their unique nuclearityand structure-dependent optical and electronic properties, but also to their potential in the development of novel nanomaterials and catalysts. Phosphine-coordinated small gold… (More)
DOI: 10.1002/anie.201102901

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