Generation and reactions of an unsubstituted N-heterocyclic carbene boryl anion.

@article{Monot2010GenerationAR,
  title={Generation and reactions of an unsubstituted N-heterocyclic carbene boryl anion.},
  author={Julien Monot and Andrey Solovyev and H{\'e}l{\`e}ne Bonin-Dubarle and {\'E}tienne Derat and Dennis P Curran and Marc Robert and Louis Fensterbank and Max Malacria and Emmanuel Lac{\^o}te},
  journal={Angewandte Chemie},
  year={2010},
  volume={49 48},
  pages={9166-9}
}
Complexation of a boron atom by an N-heterocyclic carbene has been enlisted to make an assortment of unusual lowvalent boron compounds and rare boron-containing reactive intermediates including boryl radicals 3a] and borenium ions. Such species have interesting fundamental properties and are potentially useful reagents in organic synthesis, among other applications. Nucleophilic boron reagents are extremely rare. Recent reviews list only two characterized boryl anions. The… CONTINUE READING

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Amine-boryl anions have also been used

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