# Generalized Gibbs' Phase Rule

@inproceedings{Sun2021GeneralizedGP, title={Generalized Gibbs' Phase Rule}, author={Wenhao Sun and Matthew J. Powell-Palm}, year={2021} }

Gibbs’ Phase Rule describes the nature of phase boundaries on phase diagrams and is a foundational principle in materials thermodynamics. In Gibbs’ original derivation, he stipulates that the Phase Rule applies only to “simple systems”—defined to be homogeneous, isotropic, uncharged, and large enough that surface effects can be neglected; and not acted upon by electric, magnetic or gravitational fields. Modern functional materials—spanning nanomaterials, multiferrorics, materials for energy…

## 5 Citations

### Calculation of a temperature–volume phase diagram of water to inform the study of isochoric freezing down to cryogenic temperatures

- Materials Science, PhysicsRSC advances
- 2022

Phase diagrams are integral to the application and interpretation of materials thermodynamics, and none is more ubiquitous than the common temperature–pressure diagram of water and its many icy…

### Minimization of Gibbs Energy in High-Pressure Multiphase, Multicomponent Mixtures through Particle Swarm Optimization

- Computer ScienceACS omega
- 2021

A critique of the approach is provided and suggestions for future work are provided, including a PSO-based entropy-maximization method that would enable the aforementioned continuum codes to perform on-the-fly, phase-equilibria calculations of multicomponent mixtures.

### Review of computational approaches to predict the thermodynamic stability of inorganic solids

- Materials ScienceJournal of Materials Science
- 2022

Improvements in the efficiency and availability of quantum chemistry codes, supercomputing centers, and open materials databases have transformed the accessibility of computational materials design…

### Machine-Learning Rationalization and Prediction of Solid-State Synthesis Conditions

- Materials ScienceChemistry of materials : a publication of the American Chemical Society
- 2022

There currently exist no quantitative methods to determine the appropriate conditions for solid-state synthesis. This not only hinders the experimental realization of novel materials but also…

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