{Ge9[Si(SiMe3)3]2}(2-): a starting point for mixed substituted metalloid germanium clusters.

Abstract

Deeper investigations on the silylation reaction of the Ge9(4-) Zintl anion are provided. The reaction of K4Ge9 with two equivalents of ClHyp (Hyp = Si(SiMe3)3) gives the metalloid cluster compound [Ge9(Hyp)2](2-). Subsequent reactions with this compound give access to the first mixed trisubstituted metalloid cluster [Ge9(Hyp)2(Hyp(Ph3))](-) (Hyp(Ph3) = Si… (More)
DOI: 10.1039/c5dt04022a

Cite this paper

@article{Kysliak2016Ge9SiSiMe3322AS, title={\{Ge9[Si(SiMe3)3]2\}(2-): a starting point for mixed substituted metalloid germanium clusters.}, author={Oleksandr Kysliak and A Schnepf}, journal={Dalton transactions}, year={2016}, volume={45 6}, pages={2404-8} }