Gaseous iron(II) and iron(III) complexes with BINOLate ligands.


Electrospray ionization (ESI) of dilute solutions of 1,1'-bi-2-naphthol (BINOL) and iron(II) or iron(III) sulfate in methanol/water allows the generation of monocationic complexes of iron and deprotonated BINOL ligands with additional methanol molecules in the coordination sphere, and the types of complexes formed can be controlled by the valence of the… (More)


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@article{Rochut2008GaseousIA, title={Gaseous iron(II) and iron(III) complexes with BINOLate ligands.}, author={Sophie Rochut and Jana Roithov{\'a} and Detlef Schr{\"o}der and Francesca Novara and Helmut Schwarz}, journal={Journal of the American Society for Mass Spectrometry}, year={2008}, volume={19 1}, pages={121-5} }