Gas phase behavior of radical cations of perfluoroalkyl-1,2,4-triazines: an experimental and theoretical study.


Electron ionization mass spectrometry and low-energy collision-induced decomposition reactions occurring in a tridimensional ion trap, together with density functional theory (DFT) calculations on neutrals, even- and odd-electron cations, have been used to study the gas-phase ion chemistry of a series of perfluoroalkyl-1,2,4-triazines. Loss of oxygen, due… (More)
DOI: 10.1002/jms.1622


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