Gas-phase base-catalyzed Claisen-Schmidt reactions of the acetone enolate anion with various para-substituted benzaldehydes.

Abstract

Substituent effects were determined for the gas-phase base-catalyzed Claisen-Schmidt reaction of the acetone enolate anion and various para-substituted benzaldehydes. Under chemical ionization conditions, the adduct for the reaction was detected and the fraction of adduct that is tetrahedral was determined. The Hammett constants for the substituents… (More)
DOI: 10.1016/1044-0305(95)00587-0

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