Gas phase and solution structures of 1-methoxyallenyllithium.

@article{Dixon2009GasPA,
  title={Gas phase and solution structures of 1-methoxyallenyllithium.},
  author={Darryl D. Dixon and M. A. Tius and L. M. Pratt},
  journal={The Journal of organic chemistry},
  year={2009},
  volume={74 16},
  pages={
          5881-6
        }
}
  • Darryl D. Dixon, M. A. Tius, L. M. Pratt
  • Published 2009
  • Chemistry, Medicine
  • The Journal of organic chemistry
  • A combined computational and (13)C NMR study was used to determine the solution structures of 1-methoxyallenyllithium. The gas phase calculations indicated that this species is aggregated as a hexamer. The NMR spectra in THF solution, together with the calculated aggregation energies and chemical shifts, are consistent with a dimer-tetramer equilibrium. 
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