Gas phase and solution structures of 1-methoxyallenyllithium.

  title={Gas phase and solution structures of 1-methoxyallenyllithium.},
  author={Darryl D. Dixon and M. A. Tius and L. M. Pratt},
  journal={The Journal of organic chemistry},
  volume={74 16},
  • Darryl D. Dixon, M. A. Tius, L. M. Pratt
  • Published 2009
  • Chemistry, Medicine
  • The Journal of organic chemistry
  • A combined computational and (13)C NMR study was used to determine the solution structures of 1-methoxyallenyllithium. The gas phase calculations indicated that this species is aggregated as a hexamer. The NMR spectra in THF solution, together with the calculated aggregation energies and chemical shifts, are consistent with a dimer-tetramer equilibrium. 
    15 Citations

    Topics from this paper