Further investigations on CC bond formation at the diruthenium aminocarbyne complexes [Ru2{μ-CN(Me)R}(μ-CO)(CO)2(Cp)2]SO3CF3 (R=Me, CH2Ph) and molecular structure of [Ru2(μ-CNMe2)(μ-CO)(COPh)(CO)(Cp)2]

@inproceedings{Albano1998FurtherIO,
  title={Further investigations on CC bond formation at the diruthenium aminocarbyne complexes [Ru2\{μ-CN(Me)R\}(μ-CO)(CO)2(Cp)2]SO3CF3 (R=Me, CH2Ph) and molecular structure of [Ru2(μ-CNMe2)(μ-CO)(COPh)(CO)(Cp)2]},
  author={Vincenzo G. Albano and Luigi Busetto and Chiara Camiletti and Magda Monari and Valerio Zanotti},
  year={1998}
}
Abstract The reactions of [Ru 2 { μ -CN(Me)R}( μ -CO)(CO) 2 (Cp) 2 ]SO 3 CF 3 (R=Me 1a , CH 2 Ph 1b ; Cp= η -C 5 H 5 ) with Li 2 Cu(CN)R′ 2 (R′=Me, Bu n , Ph) result in CC bond formation at the CO ligand affording the acyl complexes [Ru 2 { μ -CN(Me)R}( μ -CO)(COR′)(CO)(Cp) 2 ] 2 . The crystal structure of [Ru 2 { μ -CNMe 2 )( μ -CO)(COPh)(CO)(Cp) 2 ] 2a reveals the double bond character of the μ -CN group and the interligand interaction involving the acyl oxygen and the μ -CNMe 2 moiety… CONTINUE READING