Furostanol saponins from Tribulus terrestris.

@article{Combarieu2003FurostanolSF,
  title={Furostanol saponins from Tribulus terrestris.},
  author={Eric de Combarieu and Nicola Fuzzati and Marco Lovati and Enrico Mercalli},
  journal={Fitoterapia},
  year={2003},
  volume={74 6},
  pages={
          583-91
        }
}
An HPLC-ELSD-ESI-MS method has been developed for the analysis of the steroidal saponins in the aerial parts of Tribulus terrestris. Protodioscin, a new saponin (5,6-dihydroprotodioscin, neoprotodioscin) and their respective sulfates were detected. The structure of the new compound was elucidated on the basis of NMR and ESI-MS spectral analysis. 
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