Functionalization of acetylene-terminated monolayers on Si(100) surfaces: a click chemistry approach.

@article{Ciampi2007FunctionalizationOA,
  title={Functionalization of acetylene-terminated monolayers on Si(100) surfaces: a click chemistry approach.},
  author={Simone Ciampi and Till B{\"o}cking and Kristopher A Kilian and Michael C James and Jason B Harper and John Justin Gooding},
  journal={Langmuir : the ACS journal of surfaces and colloids},
  year={2007},
  volume={23 18},
  pages={9320-9}
}
In this article, we report the functionalization of alkyne-terminated alkyl monolayers on Si(100) using "click" chemistry, specifically, the Cu(I)-catalyzed Huisgen 1,3-dipolar cycloaddition reaction of azides with surface-bound alkynes. Covalently immobilized, structurally well-defined acetylene-terminated organic monolayers were prepared from a commercially available terminal diyne species using a one-step hydrosilylation procedure. Subsequent derivatization of the alkyne-terminated… CONTINUE READING
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