Functionalization of Unactivated C(sp3 )-H Bonds Using Metal-Carbene Insertion Reactions.


Versatile C-H insertions: Novel protocols for metal-carbene insertions using diazo compounds have been recently developed. Application of the respective rhodium and palladium catalytic systems allows formation of new carbon-carbon bonds in very good yields and selectivities. 
DOI: 10.1002/anie.201609033


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