Functionalised [ ( NHC ) Pd ( allyl ) Cl ] Complexes : Synthesis , Immobilisation and Application in Cross-Coupling and Dehalogenation Reactions

@inproceedings{Collinson2016Functionalised,
  title={Functionalised [ ( NHC ) Pd ( allyl ) Cl ] Complexes : Synthesis , Immobilisation and Application in Cross-Coupling and Dehalogenation Reactions},
  author={J Collinson and James D E T Wilton-Ely and Silvia D{\'i}ez-Gonz{\'a}lez},
  year={2016}
}
A novel NHC–palladium(II) (NHC = N-heterocyclic carbene) complex and its immobilised version have been prepared and fully characterised. Optimisation studies led to good catalytic activities in Suzuki-Miyaura cross coupling and chloroarene dehalogenation reactions. Furthermore, the unexpected palladium-mediated transfer hydrogenation of a carbonyl compound is reported. 

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