Functional Sulfur-Doped Buckybowls and Their Concave-Convex Supramolecular Assembly with Fullerenes.

Abstract

Buckybowls are fascinating components of supramolecular assemblies owing to their unique bowl-shaped π-surfaces. Herein we present a protocol for the functionalization of a sulfur-doped buckybowl, trithiasumanene, via a brominated intermediate, from which thiolated trithiasumanenes were derived. The curved surface and electron-donating properties of… (More)
DOI: 10.1002/anie.201606383

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