From bis(imidazole-2-thion-4-yl)phosphane to a flexible P-bridged bis(NHC) ligand and its silver complex.

Abstract

Synthesis of the first P(V)-bridged bis(NHC) ligand 7 was achieved via deprotonation of P(V)-functionalized bis(imidazolium) salt 6, which was obtained via oxidative desulfurization of bis(imidazole-2-thion-4-yl)phosphane 2. Bis(imidazolium) salt 6 was also employed to synthesize the corresponding silver complex 8. All new products were firmly established… (More)
DOI: 10.1039/c4dt02479f

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Cite this paper

@article{Majhi2014FromBT, title={From bis(imidazole-2-thion-4-yl)phosphane to a flexible P-bridged bis(NHC) ligand and its silver complex.}, author={P. Majhi and Gregor Schnakenburg and Rainer Streubel}, journal={Dalton transactions}, year={2014}, volume={43 44}, pages={16673-9} }