Fragmentation pathways of organoarsenical compounds by electrospray ion trap multiple mass spectrometry (MS6).

@article{Larsen2001FragmentationPO,
  title={Fragmentation pathways of organoarsenical compounds by electrospray ion trap multiple mass spectrometry (MS6).},
  author={Bo R. Larsen and C Astorga-Llorens and Maria Helena Flor{\^e}ncio and Alexandre Moniz de Bettencourt},
  journal={Journal of chromatography. A},
  year={2001},
  volume={926 1},
  pages={167-74}
}
With its detection limit well below 30 pg microl(-1) LC-MS-MS has become a sensitive and thus popular analytical technique for organoarsenical compounds. Collision induced dissociation (CID) is a valuable tool for speciation and facilitates a positive identification of the species detected. However, it is not straightforward to understand the fragmentation pathways of organoarsenical compounds when only CID-MS-MS data is available. In the present paper we have investigated multiple mass… CONTINUE READING

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