Formation of mixed-ligand zinc(II) complex-montmorillonite hybrids by solid-solid reactions.

@article{Khaorapapong2011FormationOM,
  title={Formation of mixed-ligand zinc(II) complex-montmorillonite hybrids by solid-solid reactions.},
  author={Nithima Khaorapapong and Patcharaporn Pimchan and Makoto Ogawa},
  journal={Dalton transactions},
  year={2011},
  volume={40 22},
  pages={5964-70}
}
Two luminescent hybrids, Znqb- and Znqp-montmorillonites (q = 8-hydroxyquinoline, b = 2,2'-bipyridine, p = 1,10-phenanthroline), were prepared by solid-solid reactions between Zn(II)-montmorillonite and two ligands (8-hydroxyquinoline and 2,2'-bipyridine or 1,10-phenanthroline) at room temperature. The intercalation and in situ complex formation of the two ligands into an interlayer space of Zn(II)-montmorillonite were confirmed by powder XRD, TG-DTA, as well as FT-IR, UV-vis and… CONTINUE READING

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