Formation of Bi(II) and Bi(IV) in aqueous hydrochloric solutions of Bi(III)

@article{Aleksandrov1987FormationOB,
  title={Formation of Bi(II) and Bi(IV) in aqueous hydrochloric solutions of Bi(III)},
  author={A. Iu. Aleksandrov and I E Makarov},
  journal={Bulletin of the Academy of Sciences of the USSR, Division of chemical science},
  year={1987},
  volume={36},
  pages={217-220}
}
  • A. Aleksandrov, I. E. Makarov
  • Published 10 August 1987
  • Chemistry, Materials Science
  • Bulletin of the Academy of Sciences of the USSR, Division of chemical science
Conclusions1.The formation of bismuth(II) and bismuth(IV) under the action of ionizing radiation on hydrochloric acid solutions of bismuth(III) has been shown by low-temperature and pulse radiolysis. The kinetics of bismuth(IV) disappearance at 300°K have a complex nature and would seem to be caused both by the disproportionation of bismuth (IV) and the reaction of bismuth(IV) with bismuth(II), which leads to bismuth(III).2.The properties of bismuth (IV), which is formed from the reaction of… 
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