Formation and Reactivity of the Osmium(IV)-Cyanoimido Complex [Os(IV) (bpy)(Cl)3 (NCN)](-).

Abstract

Oxo-like reactivity exists for a new series of osmium complexes such as [Os(IV) (bpy)(Cl)3 (NCN)](-) (bpy=2,2'-bipyridine, see structure) containing the cyanoimido ligand. This ligand is formed directly at the metal center by the reaction of Os(VI) -nitrido precursors with tetraethylammonium cyanide. In the cyanoimido complexes there is an extensive… (More)
DOI: 10.1002/1521-3773(20010817)40:16<3037::AID-ANIE3037>3.0.CO;2-0

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@article{Huynh2001FormationAR, title={Formation and Reactivity of the Osmium(IV)-Cyanoimido Complex [Os(IV) (bpy)(Cl)3 (NCN)](-).}, author={My Huynh and Peter S. White and Clare A. Carter and Thomas J. Meyer}, journal={Angewandte Chemie}, year={2001}, volume={40 16}, pages={3037-9} }