Fluoro[eta(3)-hydrotris(3-R-5-methylpyrazol-1-yl)borato]zinc(II): The First TpZnF Complexes, Convenient Precursors to Zinc Hydride Complexes(,).

@article{Klaeui1997Fluoroeta3hydrotris3R5methylpyrazol,
  title={Fluoro[eta(3)-hydrotris(3-R-5-methylpyrazol-1-yl)borato]zinc(II): The First TpZnF Complexes, Convenient Precursors to Zinc Hydride Complexes(,).},
  author={W. Klaeui and U. Schilde and M. Schmidt},
  journal={Inorganic chemistry},
  year={1997},
  volume={36 8},
  pages={
          1598-1601
        }
}
  • W. Klaeui, U. Schilde, M. Schmidt
  • Published 1997
  • Chemistry, Medicine
  • Inorganic chemistry
  • Fluoro[eta(3)-tris(3-R-5-methylpyrazol-1-yl)hydroborato]zinc(II) complexes, Tp(R,Me)ZnF (with R = p-Tol, t-Bu), have been prepared by metathesis of Tp(p-)()(Tol,Me)ZnOAc with KF in MeOH/THF and by reaction of KTp(t-)()(Bu,Me) with Zn(ClO(4))(2) and KF in MeOH. The molecular structure of Tp(p-)()(Tol,Me)ZnF has been determined by X-ray crystallography. Crystal data: a = 11.8719(12), c = 37.051(3) Å; trigonal, space group R3c (No. 161); Z = 6. The complex contains tetrahedrally coordinated Zn(II… CONTINUE READING
    35 Citations

    Topics from this paper